basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. According to Wikipedia: “Conductometric titration is a type of titration in which the electrolytic conductivity of the reaction mixture is continuously. Conductometric titration theory states that the end-point of the titration process is determined by means of measuring conductivity. This theory is used for colloids.

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Views Read Edit View history. It was also around this time when Willis Whitney, who was studying the interactions of sulfuric acid and chromium sulfate complexes, found the first conductometric endpoint.

In other projects Wikimedia Commons. Conductivity detectors are commonly used with ion chromatography. The conversion of conductivity to the total dissolved solids depends on the chemical composition of the sample and can vary between 0. Conductometric titration is a type of titration in which the electrolytic conductivity of clnductometric reaction mixture is continuously monitored as one reactant is added.

Retrieved condductometric ” https: This theory is used for colloids that have ionazable functional groups like latexes. A wide variety of instrumentation is commercially available.

For example, in the boiler water technology, the boiler blowdown is continuously monitored for “cation conductivity”, which is the conductivity of the water after it has been passed through a cation exchange resin. However, electrical conductance measurements can also be used as a tool to locate the end point, e. By using this site, you agree to the Terms of Use and Privacy Policy.


This type of wikipedua is not ion-specific; it can sometimes be used to determine the amount of total dissolved solids T. Shedlovsky [16]E. Conductometric titration theory can be used for either turbid or colored liquids in cases when you cannot detect the end-point by using indicators that are normal.

Generally the conductivity of a solution increases with temperature, as the mobility of the ions increases.

Conductometric Titration Theory

In this case there is no limit of dilution below which the relationship between conductivity and concentration becomes linear. January Learn how and when to remove this template message.

Other developments on this topic have been done by T. From Wikipedia, the free encyclopedia. Conductivity is also temperature-dependent.

Conductometry – Wikipedia

However, it has often been assumed that cation and anion interact to form an ion pair. Kalcher, “History of Electroanalytical Methods”.

Harold Debbi has been writing professionally since After the equivalence point is achieved the conductivity increases rapidly due to the excess OH- ions. Acid-base titrqtion and redox titrations are often performed in which common indicators are used to locate the end point e. Limiting here dikipedia “at the limit of the infinite dilution”.

Unsourced material may be challenged and removed. Moreover, Kohlrausch also found that the limiting conductivity of an electrolyte. Pitts [17]R. Beyond cation conductivity, there are analytical instruments designed to measure Degas conductivitywhere conductivity is measured after dissolved carbon dioxide has been removed from the sample, either through reboiling or dynamic degassing.

For each amount of NaOH added equivalent amount of hydrogen ions is removed. Wikipeida of reference conductivities are available for many common solutions.


Conductive measurements began as early as the 18th century, when Andreas Baumgartner noticed that salt and mineral waters from Bad Gastein in Austria conducted electricity.

Conductometric Titration Theory | Bizfluent

Ultra-pure water could achieve 18 megohms or more. This continues until the equivalence point is reached, at which one obtains a solution of sodium chloride, NaCl.

The dependence on the frequency is usually small, [4] but may become appreciable at very high frequencies, an effect known as the Debye—Falkenhagen effect. Instrumentation Reference Book 3rd. Marked increases or decrease in conductance are associated with the changing concentrations of the two most highly conducting ions—the hydrogen and hydroxyl ions.

conductometric titration

Sometimes, conductivity is given in “microsiemens” omitting the distance term in the unit. Consequently, in the titration of a strong acid with a strong base, the conductance has a minimum at the equivalence point. Therefore, if you add a solution of one electrode to another, the final conductance will rely on the occurrence of reaction.

Scallan, The determination of strong and weak acidic groups in sulfite pulps, Svensk Paperstidn. From Wikipedia, the free encyclopedia. Resistance, Ris proportional to the distance, lbetween the electrodes and is inversely proportional to the cross-sectional area of the sample, A noted S on the Figure above.